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Altairnano’s NanoSafe battery. The best battery on the market, in our opinion. Shown is a 12 volt package. 35 of these are used in Phoenix’s car. It is cheaper to purchase with the car than separate.

Batteries

This web page is devoted to providing an overview of batteries, suitable for the electric vehicle market, both available now and future possibilities. The information presented is mostly from manufacturer’s web sites. W/kg is important for PHEVs not purely electric vehicles as large battery packs have plenty of amps available for acceleration. We invite corrections and verification by experts and manufacturers.

Price remains the main obstacle and have to get a lot lower like EEStore targets before electric vehicles are practical. The $/50kWHr column is the approximate size required for about 200 mile range. Divide by 50k to get $/WHr.

Available Now

Future

Everspring Global’s chromium-fluoride-lithium battery is much higher power to weight than Altairnano’s but does not have the long cycle life. Everspring and Electrovaya are the best choices where low weight is important.

Compare Electric Vehicle Batteries

There are other technologies competing for the same market, most notably EEStor’s 31 Farad 3500 volt capacitor and fuel cells powered by hydrogen or natural gas. These come under the Future heading and need to be addressed separately . A prominent ultra-capacitor manufacturer is Maxwell Technologies. Also an encouraging article from MIT research via www.spectrum.ieee.org

A motor is designed to run from a specific voltage and a battery discharge curve is well matched to this requirement as it produces near constant voltage during its discharge cycle. Capacitor voltage drops during the discharge cycle so either an additional variable DC to DC converter has to be designed to convert the changing voltage to a constant voltage like the battery, or the motor controller has to be designed to handle a large voltage range as its input. High voltage, high current devices are very expensive so the converter will not be cheap, but since the capacitors are low cost it still looks like the best value.  Lifetime (Cycles) and peak discharge rate (W/kg) should be near infinite and dependent on associated components. It also has excellent charge retention.

Zebra batteries are a Sodium Nickel Chloride battery. The promise is that the materials are abundant and cheap. The price is high because right now the batteries are hand made and include electronics for charge balancing and temperature control. Oh yea, they have to be maintained at 300°C to operate. Would you like to be caught in an accident with a huge battery filled full of molten Sodium Nickel Chloride? Safety concerns and low power density are the prime reasons car manufacturers have avoided this technology in the past.

There is some interest in Zinc-Air fuel cells from companies like eVionyx and Power Air . They claim 200 wh/kg PA, 500 wh/kg eVionyx and 225 wh/l PA, 2000 wh/l eVionyx with low cost. These sound attractive but are not rechargeable in the normal sense. Their fuel is zinc and when used up becomes zinc oxide. The zinc oxide must be re-cycled back to pure zinc. This requires energy, transportation, and storage which requires a new infrastructure. This is one of the main problems with hydrogen fuel cells. Zinc-Air looks like a better alternative than hydrogen fuel cells but still does not have the efficiency and convenience of batteries.

Most new technology batteries:

Electrovaya, AltairNano, A123Systems, Zebra, etc., do not quote prices on their websites. Everspring Global used to quote prices on their web site. They are currently only interested in big contracts for a large number of vehicles. There is a valid reason for this, and it comes down to warranty. High voltages required for Electric Vehicles means that a large number of batteries be placed in series, and sometimes groups in parallel. The problem is charge balancing, and this is where the fancy electronics comes in. The electronics package also monitors and controls cooling/heating, and shuts the battery down (usually via opening relay contacts) for emergency conditions like  over current and fire. The battery manufacturers do not want to trust the end user, or even car manufacturers, to design adequate control and safety system for their batteries. So they typically charge $65000 to engineer a battery pack for a specific application, and of course all this electronic control adds to the price of the battery. They will not sell non-warranted batteries for fear of a bad reputation beyond their control, and will warranty only batteries with their engineered control. Everspring provides a wealth of engineering data on their batteries so the purchaser can design a control system that best fits their application.

 

Article from ZEVA on LiFePO4 battery tests.

Company

Type

WHr/kg

WHr/l

W/kg

Cycles

$/50kWHr

 

 

Lead Acid

40

65

350

400

$4500

 

 

NiMH

86

170

70

1500

$90000

 

www.valence.com

Lithium Ion

90

140

100

2000

$57150

 

Zebra

NaNiCl2

90

100

150

3000

$60000

 

Xellerion

Ni-Zn

60

120

875

500

 

 

Toshiba  SCiB

Lithium Ion

78

131

10000

5000

 

 

www.altairnano.com

Lithium Ion

90

 

7000

20000

$120000

 

Advanced Battery

Lithium Polymer

 

191

 

2000

 

 

ThunderSky

LiFePO4

94

136

 

2000

 

 

PHET  PE-1150

LiFePO4

93

213

300

2000

$39000

 

PHET 

LiFePO4 Poly

125

240

 

500

 

 

Huanya

LiFePO4

100

153

 

 

 

 

Valence  Epoch

LiFePO4

84

120

158

2000

 

 

www.a123systems.com

LiFePO4

108

230

2400

3000

$50000

 

delawarepowersystems

Lithium Ion

130

235

675

500

 

 

www.fly-power.com

Lithium Polymer

133

270

2000

 

 

 

www.saftbatteries.com

L-Ion  (VLM)

136

285

800

500

 

 

Panasonic CGR18650AF

Li-Ion (2.0 Ah)

174

417

200

500

$25000

Like Tesla’s production

Panasonic CGR18650CF

Li-Ion (2.2 Ah)

184

457

200

500

 

Like Tesla’s prototype

Panasonic CGR18650E

Li-Ion (2.5 Ah)

203

533

200

500

 

 

Panasonic 18650

Li-Ion (2.9 Ah)

230

600

 

500

 

 

www.everspring.net

Lithium Fluoride

102

330

720

1000

$35400

Price no longer listed on web site.

www.electrovaya.com

Lithium Polymer

225

470

 

 

 

 

www.electrovaya.com

Lithium Polymer

330

650

 

 

 

MN series

www.sionpower.com

Lithium Sulfur

350

350

400

 

 

 

Company

Type

WHr/kg

WHr/l

W/kg

Cycles

Target

$/50kWHr

Status

www.fireflyenergy.com

Lead foam, “3D”

37

82

700

800

 

2008 “Oasis” group 31 truck battery

www.fireflyenergy.com

Lead foam, “3D²

 

 

 

 

 

Foam for both anode and cathode.

www.eestor.us

Ultracapacitor

399*

699*

extreme

1000000

$3200

Available soon, 2008, *2006 patent

www.sionpower.com

Lithium Sulfur

600

600

400

 

 

Pilot production 2008 or 2009

www.polyplus.com

Lithium Sulfur

2600

 

 

50

 

Sold patent licenses to Sion Power.  

www.polyplus.com

Lithium Air

4000

 

 

 

 

The following quote is from http://www.delawarepowersystems.com and I think it is a particularly appropriate comment on the viability of Fuel Cell Vehicles (FCV) vs. Battery Electric Vehicles (BEV) as the CEO of Delaware Power Systems, Dr. Wu was previously the Senior Application Scientist at Ballard Power Systems, the world leader of Fuel Cell systems for cars.

“The results show that in a future economy based on renewable energy, the FCV requires production of between 2.4 and 2.6 times more energy than the BEV. The FCV propulsion system weighs 43% more, consumes three times more space onboard the vehicle for the same power output, and costs approximately 46% more than the BEV system. Further, the refueling cost of a FCV is nearly three times greater, even if we do not consider the substantial cost of building and maintaining the hydrogen infrastructure on which the FCV would depend.“

By:
Stephen S. Eaves, Eaves Devices, Inc., Charlestown, RI
stepheneaves@eavesdevices.com
And
James E. Eaves University of California, Davis*
eaves@primal.ucdavis.edu

For detail comparison (pdf), click
HERE.